The number 1 should be:
Smoking in a sedan chair carried by Stuart Schreiber (the bearded chemist) and other students. (The Schreiber information was provided by Ashutosh.)
Bob already became number 1 on the Top 5 chemist transportation modes with this picture, so we decided not give him him another number 1 place with the same picture.
1) Smoking sigars with a bald head style
2) Nuclear Fission smoking
Lise Meitner, Fritz Strassmann, Otto Hahn
3) Smoking while reading slumped in a chair with the cigarette in the mouth style
Walther Nernst
4) Smoking while leaning head on hand and staring aimlessly style
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Friedrich Bergius
5) Smoking with wriggling hands style
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Lars Onsager
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